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Journal articleMeredith W, Sun C-G, Snape CE, et al., 2006,
The use of model compounds to investigate the release of covalently bound biomarkers via hydropyrolysis
, ORG GEOCHEM, Vol: 37, Pages: 1705-1714 -
Journal articlePearson VK, Sephton MA, Franchi IA, et al., 2006,
Carbon and nitrogen in carbonaceous chondrites:Elemental abundances and stable isotopic compositions
, METEORIT PLANET SCI, Vol: 41, Pages: 1899-1918, ISSN: 1086-9379 -
Journal articleMartins Z, Watson JS, Sephton MA, et al., 2006,
Free dicarboxylic and aromatic acids in the carbonaceous chondrites Murchison and Orgueil
, Meteoritics & Planetary Science, Vol: 41, Pages: 1073-1080, ISSN: 1086-9379 -
Book chapterZolensky M E, Bland P A, Brown P, et al., 2006,
Flux of meteorites to the Earth
, Meteorites and the Early Solar System II, Editors: Lauretta, McSween, Arizona, Publisher: University of Arizona Press, Pages: 869-888, ISBN: 978-0-8165-2562-1 -
Journal articleMatrajt G, Guan Y, Leshin L, et al., 2006,
Oxygen isotope systematics of individual unmelted Antarctic micrometeorites.
, Geochimica et Cosmochimica Acta, Vol: 70, Pages: 4007-4018 -
Journal articlePerry RS, Lynne BY, Sephton MA, et al., 2006,
Baking black opal in the desert sun: the importance of silica in desert varnish, 2006, Geology, 34, 537-540
, Geology, Vol: 34, Pages: 537-540, ISSN: 0091-7613 -
Journal articleCourt RW, Sephton MA, Parnell J, et al., 2006,
The alteration of organic matter in response to ionising irradiation: Chemical trends and implications for extraterrestrial sample analysis
, Geochimica et Cosmochimica Acta, Vol: 70, Pages: 1020-1039Ionising radiation is an energy source capable of generating and altering complex organic matter. A full understanding of the radiolytic formation and devolution of organic matter is essential to appreciate the budget of organic chemicals that exist in cometary and interstellar ices, carbonaceous meteorites, and to understand the results of analyses of irradiated extraterrestrial organic matter, such as that in cometary nuclei. The effects of ionising radiation on a set of 10 naturally occurring, terrestrial organic assemblages have been revealed by pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS), carbon isotopic analysis, and stepped combustion-isotope ratio mass spectrometry (SC-IRMS). Progressive radiolytic alteration of biogenic complex-hydrocarbon mixtures induces a decrease in the average size and extent of alkylation of polyaromatic hydrocarbons (PAH) and an increase in the abundance of oxygen-containing compounds, as indicated by Py-GC-MS, and an enrichment in C-13. These changes are attributed to reactions with free radicals, produced by ionising radiation. In contrast, the progressive radiolytic alteration of bitumens proposed to have derived from the radiolytic polymerisation of methane into an organic solid produces, upon pyrolysis, PAH of increasing average size and degree of alkylation. This, the opposite of the trend observed in the irradiated complex-hydrocarbons mixtures, cannot be explained in terms of the radiolytic alteration of a pre-existing array of complex organic molecules. Instead, it suggests the gradual construction of PAH from smaller molecules, supporting the hypothesis of a methane origin. Radiolytic alteration is also associated with a previously unrecognised increase in the mean combustion temperature of organic matter. This leads to predictions regarding the combustion characteristics of the irradiated organic matter present on cometary nuclei. A full understanding of the relationship between the combustion characteristics
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Conference paperKrasa D, Williams W, Wilkinson CD, et al., 2006,
Nanosized Magnetite Particle Assemblages Produced by Electron Beam Lithography (poster)
, AGU Fall -
Journal articleSephton MA, Howard LE, Bland PA, et al., 2006,
Delving into Allende's dark secrets
, ASTRON GEOPHYS, Vol: 47, Pages: 37-38, ISSN: 1366-8781 -
Conference paperMuxworthy AR, Williams W, 2006,
Critical single-domain/multidomain grain-sizes in non-interacting and interacting elongated magnetite particles: implications for magnetosomes (poster)
, AGU Fall -
Journal articleSephton MA, 2005,
Organic matter in carbonaceous meteorites: past, present and future research
, PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, Vol: 363, Pages: 2729-2742, ISSN: 1364-503X- Author Web Link
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- Citations: 36
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Journal articleBland PA, 2005,
The impact rate on Earth
, PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, Vol: 363, Pages: 2793-2810, ISSN: 1364-503X- Author Web Link
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- Citations: 26
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Journal articleBlackhurst RL, Genge MJ, Kearsley AT, et al., 2005,
Cryptoendolithic alteration of Antarctic sandstones: Pioneers or opportunists?
, JOURNAL OF GEOPHYSICAL RESEARCH-PLANETS, Vol: 110, ISSN: 2169-9097- Author Web Link
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- Citations: 22
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Journal articleBada JL, Sephton MA, Ehrenfreund P, et al., 2005,
New strategies to detect life on Mars
, ASTRONOMY & GEOPHYSICS, Vol: 46, Pages: 26-27, ISSN: 1366-8781- Author Web Link
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- Citations: 25
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Journal articleSephton MA, Looy CV, Brinkhuis H, et al., 2005,
Catastrophic soil erosion during the end-Permian biotic crisis
, GEOLOGY, Vol: 33, Pages: 941-944, ISSN: 0091-7613- Author Web Link
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- Citations: 215
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Journal articleCollins GS, Wunnemann K, 2005,
How big was the Chesapeake Bay impact? Insight from numerical modeling
, GEOLOGY, Vol: 33, Pages: 925-928, ISSN: 0091-7613- Author Web Link
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- Citations: 95
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Journal articleFehr MA, Rehkamper M, Halliday AN, et al., 2005,
Tellurium isotopic composition of the early solar system - A search for effects resulting from stellar nucleosynthesis, Sn-126 decay, and mass-independent fractionation
, GEOCHIMICA ET COSMOCHIMICA ACTA, Vol: 69, Pages: 5099-5112, ISSN: 0016-7037- Author Web Link
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- Citations: 34
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Journal articleSchonbachler M, Rehkamper M, Fehr MA, et al., 2005,
Nucleosynthetic zirconium isotope anomalies in acid leachates of carbonaceous chondrites
, GEOCHIMICA ET COSMOCHIMICA ACTA, Vol: 69, Pages: 5113-5122, ISSN: 0016-7037- Author Web Link
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- Citations: 50
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Journal articleSephton MA, Love GD, Meredith W, et al., 2005,
Hydropyrolysis: A new technique for the analysis of macromolecular material in meteorites
, PLANETARY AND SPACE SCIENCE, Vol: 53, Pages: 1280-1286, ISSN: 0032-0633- Author Web Link
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- Citations: 25
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Journal articleBland PA, Alard O, Benedix GK, et al., 2005,
Volatile fractionation in the early solar system and chondrule/matrix complementarity
, PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, Vol: 102, Pages: 13755-13760, ISSN: 0027-8424- Author Web Link
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- Citations: 148
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